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Yes, DMS evaporates at very low temps compared to boiling, but you cannot boil off the DMS until it has been created by the thermal decomposition of SMM, which occurs at much higher temps. As noted by @AlexKay, the half life of SMM at 212°F (100°C) varies from 30 - 40 minutes, depending on pH.
SMM decomposition rate is a function of temperature (and pH.) Since the temp is 212°F (100°C) when boiling (at sea level) regardless of boil vigor, boil vigor does not affect the rate of SMM decomposition. Boil vigor will affect the rate of DMS elimination, once formed, but this is of little consequence since SMM decomposition is the rate limiting step.
The rate of SMM decomposition is significant down to about 170°F, so it is important not to cool slowly in a covered vessel, or with still wort, if there is significant remaining SMM after the boil, as this can result in excess DMS in the final beer.
Brew on
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